Synthesis of Curved Polycyclic Arenes Embedded with Oxepine and Thiepine Using Ring Expansion Strategy.
Organic letters(2023)
摘要
A tandem oxidative ring expansion of a six- to seven-membered ring was developed to construct a new class of negatively curved polycyclic arenes embedded with oxepine and thiepine, namely, dibenzo[,]phenanthro[9,10-]oxepine (DBPO) and dibenzo[,]phenanthro[9,10-]thiepine (DBPT), respectively. Mechanistic studies disclosed that an unexpected [4 + 2] cycloadduct formed between the alkene moiety of -biphenyl-linked methylenexanthenes and -chloranil serves as a radical cation or a dication equivalent that facilitates the FeCl-mediated tandem ring expansion process.
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关键词
curved polycyclic arenes,synthesis
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