Phosphine-based metal-organic layers to construct single-site heterogeneous catalysts for arene borylation.
Chemical communications (Cambridge, England)(2023)
摘要
Metal-organic layers (MOLs) are versatile platforms for creating single-site heterogeneous catalysts. Incorporating molecular functionalities into MOLs is crucial for catalysis. In this study, we synthesized phosphine-containing MOLs constructed from Hf-oxo secondary building units (SBUs) and phosphine ligands. The mono(phosphine)-Ir complexes generated by the metalation of TPP-MOL were highly active as heterogeneous catalysts for the C(sp)-H borylation of a range of arenes. This research expands the diversity of MOL-based catalysts.
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关键词
heterogeneous catalyst,phosphine-based,metal-organic,single-site
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