Synthesis of Bicyclo[1.1.0]butanes from Iodo-Bicyclo[1.1.1]pentanes

Michael D. Mandler, James Mignone, Elizabeth A. Jurica,Maximilian D. Palkowitz,Darpandeep Aulakh,Anthony N. Cauley,Christopher A. Farley,Shasha Zhang,Sarah C. Traeger,Amy Sarjeant, Anthony Paiva,Heidi L. Perez,Bruce A. Ellsworth,Alicia Regueiro-Ren

Organic letters（2023）

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摘要

We describe a two-step process for the synthesis of substituted bicyclo[1.1.0]butanes. A photo-Hunsdiecker reaction generates iodo-bicyclo[1.1.1]pentanes under metal-free conditions at room temperature. These intermediates react with nitrogen and sulfur nucleophiles to afford substituted bicyclo[1.1.0]butane products.

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synthesis,iodo-bicyclo[

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