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Strong circularly polarized luminescence via intramolecular excited-state symmetry-breaking charge separation.

Maria João Álvaro-Martins, Chloé Billiaux, Pascale Godard,Reiko Oda,Guillaume Raffy,Dario M Bassani

Chemical communications (Cambridge, England)（2023）

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Abstract
-1,2-di(1-pyrenylamino)cycloxexane was found to display circularly polarized excimer emission ( = 0.016) both in polar and non-polar solvents that is assigned to charge separation symmetry breaking on the basis of its large transition state dipole moment (12.1 D).
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Key words
luminescence,charge separation,excited-state,symmetry-breaking
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