Photosensitized Anti-Markovnikov Hydroesterification of Unactivated Alkenes
Organic letters(2023)
摘要
Hydrofunctionalization of alkenes represents a fundamental strategy in synthetic organic chemistry. Herein, we describe a visible-light-promoted approach for the anti-Markovnikov hydrooxygenation of unactivated alkenes. Our protocol features the utilization of a cost-effective, bench-stable, and easy-to-handle oxime ester as the reagent, enabled by energy-transfer catalysis. This methodology exhibits excellent functional group tolerance and mild reaction conditions, rendering it suitable for the hydroesterification of pharmaceutically relevant molecule-derived alkenes.
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关键词
anti-markovnikov
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