Densified graphene-like carbon nanosheets with enriched heteroatoms enabling superior gravimetric and volumetric potassium storage capacities.
Journal of colloid and interface science(2023)
Abstract
Constructing carbon electrodes with abundant heteroatoms and appropriate graphitic interlayer spacing remains a major challenge for achieving high gravimetric and volumetric potassium storage capacities with fast kinetics. Herein, we constructed 3D graphene-like N, F dual-doped carbon sheets induced by Ni template (N, F-CNS-Ni) with dense structure and rich active sites, providing a promising approach to address the facing obstacles. Highly reversible K-ion insertion/extraction is realized in the graphitic carbon structure, and K-adsorption capability is enhanced by introducing N/F heteroatoms. As a result, the N, F-CNS-Ni electrode exhibits ultrahigh gravimetric and volumetric capacities of 404.5 mA h g and 281.3 mA h cm at 0.05 A/g, respectively, and a superb capacity of 259.3 mA h g with a capacity retention ratio of 90 % even after 600 cycles at 5 A/g. This work presents a simple Ni-based template method to prepare graphene-like carbon nanosheets with high packing density and rich heteroatoms, and offers mechanism insight for achieving superior K-ion storage.
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Key words
Potassium ion battery,Carbon nanosheet,Graphene,Anode,Heteroatoms
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