Unraveling the role of unpaired 3d electrons in eg orbital of CoO: Driving π feedback of N2 for efficient ammonia electrosynthesis

Yuanyuan Xiong,Liang Zhao,Rui Zhao,Xiaoxuan Wang,Xinyue Chi,Kaixin Zhang,Zhenzhen Fu,Shuyuan Li,Jiaou Wang,Kaiqi Nie,Zhiyu Yang,Yi-Ming Yan

Chemical Engineering Journal（2023）

引用 0|浏览6

暂无评分

摘要

•The prominent activity of CoO depends on its unique d electronic structure.•The unpaired electrons in eg orbital of Co2+ site promote the π-feedback process from CoO to N2.•We characterized the electronic structure of samples and analyze the reaction mechanism.

查看译文

关键词

π feedback,D electron,Electrocatalysis,Ammonia synthesis,Cobalt oxide

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要