Synthesis, characterization, and enhanced hydrogen generation from NaBH4 methanolysis of highly dispersed bimetallic PdNi nanoparticles supported on Vulcan carbon

Rozhin Darabi,Qiang Gu,Abbasali Abouei Mehrizi,Elif Esra Altuner,Wael Alhrasishawi,Fulya Gulbagca,Rima Nour Elhouda Tiri, Yener Tekeli,Abdullah Seyrankaya,Idris Kaynak,Fatih Sen

Molecular Catalysis（2023）

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Abstract

•PdNi@VC NPs were synthesized by chemical method.•The average size of the NPs was found to be 8.523 ± 2.036 nm.•Hydrogen production and catalytic studies were carried out using PdNi@VC NPs.•The resulting hydrogen production efficiency was found to be 84%.•Ea, ΔH, and ΔS values were found as 54.2 kJ/mol, 51.7 kJ/mol, -134.5 J/mol.K, respectively.

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Key words

bimetallic pdni nanoparticles,nabh4 methanolysis,hydrogen generation

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