Excellent high-temperature dielectric energy storage of flexible all-organic polyetherimide/poly(arylene ether urea) polymer blend films
Journal of Power Sources(2023)
摘要
Current commercial dielectric polymers can scarcely meet the increasing demand for advanced capacitors under harsh thermal conditions up to 150 °C due to the severely degraded efficiency at high electric field and high temperature. Here, we design and prepare all-organic polyetherimide/poly(arylene ether urea) polymer blend films which exhibit a record-high discharged energy density of ∼4.84 J/cm3 with an efficiency higher than 90% at 150 °C among the reported free-standing all-organic polymer-based dielectrics. Moreover, the capacitive energy storage performance shows an excellent temperature stability from room temperature to 150 °C, and a great long-term reliability over 20,000 cycles is achieved under working conditions of 200 MV/m and 150 °C in hybrid vehicles. These excellent dielectric energy storage performances benefit from the introduction of molecular trapping centers which notably reduce the high-temperature conduction loss. Our research provides a convenient and effective method to develop high-temperature polymer dielectrics.
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关键词
Capacitor, Dielectric polymer, High temperature, Energy storage
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