Catalytic aerobic desulfurization of fuels in the presence of nanosized mixed carbide FeWC
Chemical Engineering Journal(2023)
摘要
•Mixed carbide (FeWC) was successfully applied in aerobic desulfurization.•Synthesis by microwave irradiation allows to obtain a nanoscale catalyst in 15 min.•Dibenzothiophene can be completely oxidized in 1 h at 130 °C, 6 atm air pressure.•Total sulfur content in straight-run gasoline can be reduced from 996 to 6 ppm.•The catalyst retains its activity for at least 5 cycles of oxidation-regeneration.
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关键词
Oxidative desulfurization,Air,Mixed carbide tungsten-iron,Nanocatalyst,Microwave synthesis
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