Ultrasmall Ag nanoparticles on photoactive metal-organic framework boosting aerobic cross-dehydrogenative coupling under visible light

Yan Che,Xin Liu,Mengying Li,Xingbing Liu, Meidan Wang, Qihui Song,Hongzhu Xing

Applied Surface Science（2023）

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摘要

•Composite of MOF and Ag explored firstly for visible-light-mediated CDC.•Photoactive MOF generates simultaneously singlet oxygen and superoxide radical.•Ultrasmall Ag NPs enhance photocatalytic reaction via Schottky barrier.•Direct interaction between Ag NPs and substrate of tertiary amine.

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关键词

MOF,Ag nanoparticles,Photocatalyst,Aerobic CDC

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