Solubility measurement, correlation and thermodynamic properties of 2,3,4-trichloro-1,5-dinitrobenzene in fifteen mono-solvents at temperatures from 278.15 to 323.15 K

Chinese Journal of Chemical Engineering(2023)

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Abstract
The solubility of 2,3,4-trichloro-1,5-dinitrobenzene (TCDNB) was measured by a laser dynamic method over the temperature range from 278.15 K to 323.15 K under 0.1 MPa in fifteen mono-solvents (methanol, ethanol, isopropanol, n-butanol, toluene, dichloromethane, chloroform, tetrachloromethane, 1,2-dichloroethane, acetone, ethyl acetate, acetonitrile, N-methylpyrrolidone (NMP), N,N-dimethylformamide dimethyl sulfoxide (DMF), dimethyl sulfoxide (DMSO). The solubility of TCDNB could be increased with increasing temperature in fifteen mono-solvents. TCDNB solubility is in the fol-lowing order at 298.15 K: NMP>DMF>DMSO>toluene>acetone>ethyl acetate>dichloromethane>1,2-dich-loroethane>chloroform>acetonitrile>tetrachloromethane>methanol>ethanol>n-butanol>isopropanol. The KAT-LSER model was used to investigate the solvent effect, which revealed that the hydrogen bond acidity of solvents has a greater effect on TCDNB solubility. The van't Hoff model, the modified Apelblat model, the kh model, and the non-random two liquid (NRTL) model were used to correlate the solubility of TCDNB. The calculated solubility data agreed well with the experimental data, and the modified Apelblat model fit best. Furthermore, the van't Hoff and Gibbs equations were also used to calculate the dissolution thermodynamic properties of TCDNB in various solvents. TCDNB dissolution could be an enthalpy-driven, non-spontaneous, and endothermic process in fifteen mono-solvents. The determi-nation and fitting solubility of TCDNB, as well as the calculation of its thermodynamic properties, would be critical in the purification and crystallization of its preparation process research. & COPY; 2022 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd.
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Key words
2,3,4-Trichloro-1,5-dinitrobenzene (TCDNB),Solid-liquid equilibrium,Laser dynamic method,Solubility model,Thermodynamics properties
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