Comparison of Granites from the Eastern and Western Districts of the Gejiu Ore District in South China: Implication for Petrogenesis and Tin Metallogeny

Late Cretaceous granitoids are developed in the eastern and western districts of the Gejiu ore district, but tin deposits mainly occur in the eastern district, and the reasons for the difference in mineralization between the eastern and western districts are still controversial. Considering the main factors controlling granite Sn fertility, the whole-rock geochemical characteristics of granites on both sides are compared. LA-ICP-MS zircon U-Pb analyses of the Gejiu granites yielded two age periods: the early phase from 79.2 to 83.3 Ma and the later phase from 73.8 to 75.6 Ma. The western district granites have higher zircon e(Hf)(t), CaO/Na2O, Ba, and Sr concentrations and lower Rb/Sr ratios than the eastern district granites, indicating that the western district granites have more mantle-derived materials in the source than the eastern district granites. Results of oxygen fugacity show that the western granites have a higher oxygen fugacity condition. More depleted Ba, Sr, P, Eu and Ti characteristics with obviously negative Eu anomalies in the eastern granites also have high Rb/Sr ratios and low Nb/Ta and Zr/Hf ratios, indicating that the eastern granites experienced highly magmatic differentiation, attributed to high volatile F contents that can reduce the viscosity and solidus of magma. Combined with the differences in field observations and structural styles, on the whole, the western district granites have higher oxygen fugacities and lower F contents and magmatic differentiation than those in the eastern district granites, indicating that the western district granites are not conducive to mineralization.