Study of the Mechanical Behaviour of Al–Cu–Fe Quasicrystalline Coatings Across a Broad Range of Temperatures

Yu.V. Milman,M. O. Iefimov, A. A. Golubenko,Wang Changliang,Li Zhang, Zhu Chonggao,Tian Haoliang

POWDER METALLURGY AND METAL CERAMICS(2023)

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摘要
The mechanical behavior of Al 63 Cu 25 Fe 12 quasicrystalline coatings in the temperature range of 77–1073 K was studied by the microindentation method. Coatings with a thickness of 350 μm were obtained on the substrate of steel 45 by high-speed air-fuel spraying of water-atomized powders with a size fraction of 40–80 μm. The content of the icosahedral quasicrystalline phase in the coatings after production was 75 wt.%. Annealing at 998 K for 20 min made it possible to obtain 100% of the quasicrystalline phase in the coating. The microhardness of the studied coatings at a temperature of 77 K and room temperature (293 K) is ~7 GPa and slightly decreases to a level of ~4.5 GPa at a temperature of 725 K, followed by a sharp decrease to 1.5–1 GPa at 923–973 K. Analysis of the temperature dependence of the plasticity characteristic δ H , determined by the indentation method, showed that up to a temperature of 873 K, the quasicrystalline coatings of the Al–Cu–Fe system have the brittleness during compression/tension tests, and above 873 K they start to possess a macroplasticity. Calculation of the value of δ H in a wide temperature range makes it possible to predict the mechanical properties of brittle, at standard test methods, quasicrystalline coatings of the Al–Cu–Fe system.
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关键词
quasicrystals,coatings,hardness,microindentation in the temperature range,plasticity characteristic
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