Carbon layer-protected self-supporting CoSe2 nanowire arrays for durable hydrogen evolution reaction catalysts
SUSTAINABLE ENERGY & FUELS(2023)
摘要
Cobalt diselenide (CoSe2) is considered a promising catalyst for hydrogen evolution reaction (HER); however, the limited active number, agglomeration, and quick deactivation by acid etching hinder its broad adoption. Herein, we report carbon layer-covered CoSe2 nanowire arrays grown on carbon cloth (C@CoSe2/CC). The structure of the nanowire array demonstrates synergistic effects in promoting the infiltration of electrolytes, accelerating the diffusion of H-2 bubbles, and preventing CoSe2 from being etched by the electrolyte. Consequently, the overpotential and Tafel slope (193 mV, 54.3 mV dec(-1)) obtained sustained 24 h with a negligible overpotential deterioration. This study provides insights into optimizing the intrinsic activity of active sites.
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关键词
nanowire arrays,cose<sub>2</sub>,catalysts,hydrogen,layer-protected,self-supporting
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