Reducing O2 sensitivity in electrochemical nitric oxide releasing catheters: An O2-tolerant copper(II)-ligand nitrite reduction catalyst and a glucose oxidase catheter coating

Corey J. White, Jeremey M. Schwartz,Nicolai Lehnert,Mark E. Meyerhoff

Bioelectrochemistry（2023）

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Abstract

•Increased NO fluxes from electrochemical IV-catheters in O2-rich environments.•O2-tolerant copper(II)-ligand complex.•Mitigated O2 diffusion into the catheter material via immobilized oxidase enzyme.•Highest NO fluxes reported thus far in >3% O2 saturated solutions.

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Key words

Nitric oxide,Copper (II) complex,Intravenous catheters,Electrochemical nitrite reduction,Glucose oxidase

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