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1,2-Arylsulfonylation of Vinyl Ethers and Esters Enabled by Dual Ni Catalysis

Lucas V. B. L. Pugnal,Kimberly B. Vega,Emanuele F. Pissinati,Jose Tiago M. Correia,Julio Zukerman-Schpector,Ruben Martin,Marcio W. Paixao

CHEMCATCHEM（2023）

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Abstract
A dual photocatalytic sulfonylation-arylation of electron-rich alkenes is described. By combining sulfinate salts, (hetero)-aryl-bromides and 2,3-dihydrofuran under Ru and Ni dual catalysis, over 35 examples of aryl-sulfonylated scaffolds could be obtained in good to excellent yields, under mild reaction conditions and high diastereoselectivity.
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Key words
sulfonyl-arylation,diastereoselective,dual catalysis,difunctionalization,photoredox
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