Hierarchical porous yolk-shell Co-N-C nanocatalysts encaged ingraphene nanopockets for high-performance Zn-air battery
NANO RESEARCH(2023)
摘要
The rational design and preparation of promising cathode electrocatalysts with excellent activity and strong stability for metal-air batteries is a huge challenge. In this work, we innovate an approach of combining solvothermal with high-temperature pyrolysis utilizing zeolitic imidazolate framework (ZIF)-8 and ZIF-67 as the template to synthesize a novel hybrid material of hierarchical porous yolk-shell Co-N-C polyhedron nanocatalysts engaged in graphene nanopocket (yolk-shell Co-N-C@GNP). The obtained catalyst exhibits prominent bifunctional electrocatalytic performance for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in the alkaline condition, in which the half-wave potential is 0.86 V for ORR, and the over-potential for OER is 0.42 V at 10 mA·cm −2 . The rechargeable aqueous Zn-air battery fabricated with yolk-shell Co-N-C@GNP cathode deliveries an open circuit voltage (OCV) of 1.60 V, a peak power density of 236.2 mW·cm −2 , and excellent cycling stability over 94 h at 5 mA·cm −2 . The quasi-solid-state Zn-air battery (ZAB) using yolk-shell Co-N-C@GNP displays a high OCV of 1.40 V and a small voltage gap of 0.88 V in continuous cycling tests at 2 mA·cm −2 . This work provides a valuable thought to focus attention on the design of high-efficient bifunctional catalysts with hierarchical porous yolk-shell framework and high-density metal active sites for metal-air battery technologies.
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关键词
zeolitic imidazolate framework (ZIF)-67@ZIF-8,yolk-shell,graphene nanopocket,Bi-functional catalysts,Zn-air battery
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