Effects of OH radical and SO<sub>2</sub> concentrations on photochemical reactions of mixed anthropogenic organic gases

Abstract. Vehicle exhaust, as a major source of air pollutants in urban areas, contains a complex mixture of organic vapors including long-chain alkanes and aromatic hydrocarbons. The atmospheric oxidation of vehicle emissions is a highly complex system as the co-existing inorganic gases (e.g., NOx and SO2) from other urban sources, and therefore remains poorly understood. In this work, the photooxidation of n-dodecane, 1,3,5-trimethylbeneze, and their mixture are studied in the presence of NOx and SO2 to mimic the atmospheric oxidation of urban vehicle emissions (including diesel and gasoline vehicles), and the formation of ozone and secondary aerosols are investigated. It is found that ozone formation is enhanced by higher OH concentration and higher temperature, but is influenced little by SO2 concentration. However, SO2 can largely enhance the particle formation in both number and mass concentrations, likely due to the promoted new particle formation and acid-catalyzed heterogeneous reactions from the formation of sulfuric acid. In addition, organo-sulfates and organo-nitrates are detected in the formed particles, and the presence of SO2 can promote the formation of organo-sulfates. These results provide a scientific basis for systematically evaluating the effects of SO2, OH concentration, and temperature on the oxidation of mixed organic gases in the atmosphere that produce ozone and secondary particles.