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[Pt1Ag37(SAdm)21(Dppp)3Cl6]2+: intercluster transformation and photochemical properties

Yaru Zhen,Shan Jin,Xi Kang,Chang Xu,Cao Fang,Daqiao Hu,Manzhou Zhu

Inorganic Chemistry Frontiers（2022）

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Abstract
A novel [Pt1Ag37(SAdm)21(Dppp)3Cl6]2+ nanocluster is reported, and the reaction with PPh3 triggers an intercluster transformation into [Pt1Ag28(SAdm)18(PPh3)4]2+. Using chiral Bdpp, the enantiomeric Pt1Ag37(SAdm)21(R/S-Bdpp)3Cl6 can be prepared.
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