Nickel^II-catalyzed asymmetric photoenolization/Mannich reaction of (2-alkylphenyl) ketones

Liangkun Yang, Wang-Yuren Li,Liuzhen Hou,Tangyu Zhan,Weidi Cao,Xiaohua Liu,Xiaoming Feng

Chemical Science（2022）

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摘要

A diastereo- and enantioselective photoenolization/Mannich (PEM) reaction of (2-alkylphenyl) ketones with benzosulfonimides is realized by a chiral N,N′-dioxide/NiII complex catalyst.

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NickelII-catalyzed asymmetric photoenolization/Mannich reaction of (2-alkylphenyl) ketones

Nickel^II-catalyzed asymmetric photoenolization/Mannich reaction of (2-alkylphenyl) ketones