Access to 5-bromopentanal and 6-bromohexanal derivatives via the bromination/hydrolysis of C,O-bis-zirconocenes generated from unsaturated Weinreb amides
Organic & Biomolecular Chemistry(2022)
Abstract
Direct access to bromo-aldehydes from bis-zirconocenes, generated from unsaturated amides, involving sequential C-bromination/zircona-aminal hydrolysis is reported. Potential synthetic applications are also described.
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