Electrostatic energy storage performances of La(Ni 2/3 Ta 1/3 )O 3 ‐modified Na 0.5 Bi 0.5 TiO 3 lead‐free ceramics
Journal of the American Ceramic Society(2023)
摘要
Abstract Ceramic capacitors with high electrostatic energy storage performances have captured much research interest in latest years. Sodium bismuth titanate (Na 0.5 Bi 0.5 TiO 3 )‐based ferroelectric ceramics show great potential due to their environment‐friendly composition, high polarization, and excellent relaxor properties. However, the nonergodic relaxor state of Na 0.5 Bi 0.5 TiO 3 ‐based ceramics hampers the decrement of remanent polarization, leading to poor energy storage performance. Herein, the (1 − x )Na 0.5 Bi 0.5 TiO 3 – x La(Ni 2/3 Ta 1/3 )O 3 ceramics were designed to generate the transformation between nonergodic and ergodic relaxor state. As a result, the ceramics exhibit improved dielectric relaxation, slim polarization–electric field loops, and flattened current–electric field curves due to highly dynamic polar nanoregions. Particularly, the 0.85Na 0.5 Bi 0.5 TiO 3 –0.15La(Ni 2/3 Ta 1/3 )O 3 ceramics show large breakdown electric field E b (345 kV/cm), high recoverable energy density W rec (3.6 J/cm 3 ), and efficiency η (80.6%), revealing potential applications in electrostatic energy storage.
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关键词
electrostatic energy storage performances,ceramics
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