[2]Rotaxanes featuring minimal helical axles

Jorge Meijide Suárez,Vicente Martí-Centelles,Arnaud Tron, Thierry Buffeteau,Stéphane Massip,Céline Olivier,Isabelle Pianet,Cybille Rossy,Jean-Marc Vincent, Nathan McClenaghan

crossref（2023）

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摘要

α,ω-Stoppered perfluorous domains act as rigid and chiral linear helical elements in rotaxane constructs. Dynamic NMR shows modified ring dynamics over 4–orders of magnitude compared to hydrocarbon analogues, while vibrational-CD shows stopper-induced preferential axle chirality.

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