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Enantioselective rhodium-catalyzed addition of arylboronic acids to N-heteroaryl ketones: synthesis of α-hydroxy acids

Jinbin Zhu, Zhenyue Li,Jiaqi Li,Duanshuai Tian,Ronghua Xu, Zhiyong Tan,Zhengwang Chen,Wenjun Tang

Chemical Science（2023）

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Abstract
Efficient asymmetric addition of aryl/heteroarylboronic acids to N-heteroaryl ketones is established by employing the Rh-WingPhos catalyst, affording a variety of chiral α-heteroaryl alcohols. The method provides a practical access to chiral tertiary α-hydroxyl acids.
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Key words
arylboronic acids,synthesis,rhodium-catalyzed
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