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Computational insights into the [Ni]H-catalyzed remote C(sp3)–H hydroamidation of alkenes: mechanism and insertion selectivity

Juping Wang,Zhenjie Zheng,Zijie Lin,Rongxing Xiao,Tifang Miao

Catalysis Science & Technology（2022）

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Abstract
A complete mechanism of the [Ni]H-catalyzed remote C(sp3)–H hydroamidation of alkenes was established and the origin of insertion selectivity was revealed.
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