Short-Range Slowdown of Water Solvation Dynamics around SO42- - Mg2+ Ion Pairs

Achintya Kundu,Shavkat I. Mamatkulov,Florian N. Brünig,Douwe Jan Bonthuis,Roland R. Netz,Thomas Elsaesser,Benjamin P. Fingerhut

The International Conference on Ultrafast Phenomena (UP) 2022（2022）

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摘要

2D-IR spectroscopy in the fingerprint region of SO42- ions in water reveals a counterion specific slowdown of solvation dynamics. Hydration structures of solvent shared SO42- - Mg2+ ion pairs are identified as the molecular origin.

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