A new transient directing group diethoxyethyl-l-proline facilitates ortho-arylation of aryl-amines/-amino acids via Pd-catalyzed C(sp²)–H activation

Organic & Biomolecular Chemistry（2023）

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摘要

Diethoxyethyl-l-proline (DEP) has been introduced as a new TDG for Pd-catalyzed ortho-arylation of arylamines and aromatic amino acids such as benzylamine, phenethylamine, phenylglycine, and phenylalanine.

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A new transient directing group diethoxyethyl-l-proline facilitates ortho-arylation of aryl-amines/-amino acids via Pd-catalyzed C(sp2)–H activation

A new transient directing group diethoxyethyl-l-proline facilitates ortho-arylation of aryl-amines/-amino acids via Pd-catalyzed C(sp²)–H activation