Bulk and nanoscale semiconducting materials: Structural advances using solid-state NMR spectroscopy
Current Opinion in Colloid & Interface Science(2022)
Abstract
Solid-state nuclear magnetic resonance (NMR) spectroscopy continues to make major strides in the investigation of semiconducting materials. As an analytical technique, NMR offers an element-specific probe of virtually any chemical system and is uniquely suited to the selective study of materials exhibiting disorder or inhomogeneity, where long-range structural techniques may fail. With the advances in experimentation, hardware and high-polarization techniques realized over the past decade, challenging studies on difficult nuclei from bulk to nano-sized materials have now become practical. Below, we feature five recent works that have advanced our atomic-level understanding of new semiconducting materials using NMR spectroscopy.
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Key words
Perovskites,Kesterites,Photovoltaics,Nanomaterials,Optical,Solid-state NMR,DNP NMR,NQR,Disorder,Silicon,CdSe,Phase Transition,Doping,Substitution,Degredation
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