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Impact of O3/P3 phase transition on the performance of the NaxTi1/6Mn1/6Fe1/6Co1/6Ni1/6Cu1/6O2 cathode material for Na-ion batteries

Janina Molenda, Anna Milewska, Wojciech Zając, Katarzyna Walczak, Marta Wolczko, Anna Komenda, Janusz Tobola

Journal of Materials Chemistry A（2023）

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Abstract
Ordering in the transition metal sublattice in the O3 phase affects the density of states near EF. Due to the low conductivity of the O3 phase its presence causes stronger polarization of the electrode and makes P3 → O3 phase change unfavourable.
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Key words
o3/p3 phase transition,phase transition,cathode material,na-ion
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