Influence of non-covalent interactions on the coordination geometry of Ni(ii) in Ni(ii)–M(ii) complexes (M = Zn and Hg) with a salen-type N₂O₂ Schiff base ligand and thiocyanate ion as the coligand

Lakshmi Kanta Das,Pradip Bhunia,Rosa M. Gomila,Antonio Frontera,Ashutosh Ghosh

CrystEngComm（2023）

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Abstract

The effect of non-covalent interactions on the coordination geometry of Ni(ii) in a Ni(ii)–Zn(ii) and a Ni(ii)–Hg(ii) complexes has been studied using DFT calculations.

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Key words

schiff base ligand,complexes,coordination geometry,ni<scp>ii</scp>,non-covalent,salen-type

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Influence of non-covalent interactions on the coordination geometry of Ni(ii) in Ni(ii)–M(ii) complexes (M = Zn and Hg) with a salen-type N2O2 Schiff base ligand and thiocyanate ion as the coligand

Influence of non-covalent interactions on the coordination geometry of Ni(ii) in Ni(ii)–M(ii) complexes (M = Zn and Hg) with a salen-type N₂O₂ Schiff base ligand and thiocyanate ion as the coligand