In-depth structural characterization of the influence of Li⁺ excess on spherical, Co-free layered LiMn_0.5Ni_0.5O₂ cathode material using correlative Raman–SEM microscopy

Florian Klein,Claudia Pfeifer,Philipp Scheitenberger,Lukas Pfeiffer,Dominik Zimmer, Margret Wohlfahrt-Mehrens,Mika Lindén,Peter Axmann

Journal of Materials Chemistry A（2023）

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摘要

Structural evidence of a Li+ induced phase segregation on particle level in Co-free layered Li–Mn–Ni-oxide cathode materials for Li-ion batteries is presented, illustrating the importance of correlative SEM–Raman microscopy in battery research.

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In-depth structural characterization of the influence of Li+ excess on spherical, Co-free layered LiMn0.5Ni0.5O2 cathode material using correlative Raman–SEM microscopy

In-depth structural characterization of the influence of Li⁺ excess on spherical, Co-free layered LiMn_0.5Ni_0.5O₂ cathode material using correlative Raman–SEM microscopy