Changes of Active Particulate Uranium Under the Water-Sediment Regulation Scheme in the Lower Yellow River: Potential Impact to the Uranium Flux into the Global Ocean

With the annual Water-Sediment Regulation Scheme (WSRS) transporting large amounts of suspended particulate matter (SPM) to the sea within several days, the behavior of uranium in the Yellow River during the WSRS is crucial to better understand the uranium flux. In this study, the active forms (the exchangeable, carbonate bounded, Fe/Mn oxides bounded, organic matter bounded) and the residual form of particulate uranium were extracted by the sequential extraction method and their uranium contents were measured respectively. Results show that the content of total particulate uranium was 1.43-2.56 μg/g and the active forms accounts for 11-32 %. Particle size and redox environment are the two main factors controlling the active particulate uranium. The flux of active particulate uranium at Lijin was 4.7 tons during 2014 WSRS, which was about 50 % of the dissolved uranium flux for the same period. Thus, the terrestrial uranium flux is significantly modified by artificial regulation.