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Structural Evolution of CL-20/DNB Cocrystals at High Temperature: Phase Transition and Kinetics of Thermal Decomposition

Spectrochimica acta Part A, Molecular and biomolecular spectroscopy(2023)

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摘要
completely, leading to lattice collapse of cocrystal; simultaneously, CL-20 undergoes a transition process from beta phase to gamma phase. Ultimately, gamma-CL-20 gradually decomposes with increasing temperature. The activation energy of cocrystal is also obtained as 129 +/- 10 kJ/mol. The understanding of cocrystal explosive was deepened and the further application was promoted.
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关键词
Cocrystals,Phase transition,Kinetics of decomposition
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