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Transition metal cations catalyze 16O/18O exchange of catechol motifs with H218O

Roelant Hilgers,Judith Bijlsma,Luana Malacaria,Jean-Paul Vincken,Emilia Furia,Wouter J. C. de Bruijn

Organic & Biomolecular Chemistry（2022）

Cited 2|Views5
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Abstract
In the presence of Fe(iii) and several other cations, catechol motifs undergo rapid 16O/18O exchange with H218O under mild conditions. This opens up synthetic possibilities and may have implications for studies using H218O as a mechanistic probe.
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transition metal cations,catechol motifs
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