Sustainable chicken manure-derived carbon as a metal-free bifunctional electrocatalyst in Zn-air battery
THE INTERNATIONAL CONFERENCE ON ADVANCED MATERIAL AND TECHNOLOGY (ICAMT) 2021AIP Conference Proceedings(2022)
摘要
Bifunctional catalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are needed to improve the kinetics of cathode reaction in rechargeable Zn-air batteries. In this work, using poultry waste (i.e., chicken manures) as the raw material, biomass-derived carbon catalyst is obtained via activation treatment followed by a facile pyrolysis method. The chicken manures impregnated by KOH solution and pyrolyzed at high temperature produce a porous carbon structure with a large surface area of 730.57 m2 g−1 that is beneficial for its catalytic activity. The metal-free carbon-based catalyst exhibits a promising bifunctional catalytic activity in 0.1 M KOH, showing an ORR onset potential of 0.84 V vs. RHE and an OER overpotential of 420 mV at 1 mA cm−2. The rechargeable Zn-air battery with chicken manure-derived carbon catalyst exhibits a peak power density of 30.05 mW cm−2 and excellent cycle stability performance up to 120 discharge/charge cycles. The strategy of converting animal waste into the bifunctional oxygen electrocatalysts demonstrates the viability of biomass waste conversion into value-added material.
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关键词
carbon,manure-derived,metal-free,zn-air
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