Integration of nitrogen-doped carbon dots onto active layer of forward osmosis membrane for highly efficient antibacteria and enhanced membrane performances
Journal of Environmental Chemical Engineering(2023)
摘要
Biofouling severely hampered the development of thin-film composite (TFC) forward osmosis (FO) membrane. Herein, novel nitrogen-doped carbon dots (N-C-dots) with fluorescence and long-lived afterglow dual-emission were fabricated using Na2EDTA and urea as co-precursors. The N-C-dots aqueous solution can synchronously produce superoxide anion radical (O-2(-)) and singlet oxygen (O-1(2)) under light irradiation, exhibiting immense nanoenzyme activities. The membranes (PEI-M and N-C-dots/PEI-M) were prepared by grafting PEI and N-Cdots/polyethyleneimine nanocomposites (N-C-dots/PEI) onto the active layer of pristine TFC FO membrane (Control-M), respectively. The N-C-dots/PEI-M exhibited much better hydrophilicity and smoothness than Control-M and PEI-M, resulting in a higher water permeability. Most significantly, N-C-dots/PEI-M possessed a unique dual-mode biofouling resistance, which responded to the potentials of N-C-dots as oxidase mimic and photosensitizer. In dynamic sewage treatment test, N-C-dots/PEI-M displayed much lower reduction in water flux and much better anti-biofouling behavior. Results above demonstrated that the modification strategy with N-Cdots/PEI is highly effective, pioneering a new horizon for the highly efficient inhibition of biofilm growth and biofouling development under visible light.
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关键词
Carbon dots (C-dots), Oxidase mimics, Photosensitizer, Biofouling resistance, TFC FO membrane
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