Fluid-rock chemical-physical equilibrium/disequilibrium inferred from tectonic carbonates in the Apennines (Italy): an advanced approach to track seismic cycles and earthquakes

<p>Geofluids play an important role to seismic faulting both at hypocentral depth during earthquake nucleation and at shallower crustal levels during seismic rupture propagation. Pre- to co-seismic anomalies of crustal fluid circulation have thus far been identified by hydrogeochemical and seismological (Vp/Vs) monitoring and are generally interpreted as potential precursors, triggers, and/or facilitators of large magnitude earthquakes. Structural and geochemical studies on syn-tectonic mineralizations have highlighted different patterns of fluid ingress, circulation and fluid-rock interaction during the seismic cycle of thrusts and normal faults. Understanding fault rock-fluid relationships in exhumed faults is useful for revealing the role of fluids also in still ongoing seismic cycles from different tectonic settings. We present a review of published studies and original data on the chemical-physical characteristics of syn-tectonic mineralizations formed by fluids that assisted fault-related deformation in the Apennines (Italy). We use our data to build a general model of fluid circulation during thrusting and normal faulting during the seismic cycle, and define a multi-technique workflow to identify tectonic-related physical/chemical equilibria/disequilibria in fluid-rock systems. The proposed workflow relies upon multiscale structural analysis, stable C, O, and clumped isotope analysis, radiometric dating and burial-thermal modeling. The chosen study area is the Central Apennines fold-and-thrust belt, where post-orogenic extensional deformation, characterized by numerous Mw &#8805; 6.5 earthquakes, currently overprints Neogene-Quaternary folds and thrusts. We show that thrusting mostly develops in closed fluid systems where fluid and host rock are close to chemical equilibrium. Subsequent normal faulting is characterized by a dominant upward and/or downward open fluid circulation system with an overall range of &#948;¹⁸O of paleofluids from -10&#8240; to +13.5&#8240; (V-SMOW). Isotopic and thermal fluid-rock disequilibria are particularly evident during pre-/ and co-seismic extensional deformation with mineralizations that are up to 30&#176; C warmer and 16&#176; C colder than the host rock and are associated with the ingress of exotic (meteoric or deep crustal) fluids.</p>