Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides

Yuting Chen,Guanghui Lv,Zhiyang Li, Meiling Ye,Tianle Huang,Li Hai,Yong Wu

Green Synthesis and Catalysis（2023）

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摘要

The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate scope and great functional group tolerance.

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关键词

Pyridotriazole,Sulfide,[2,3]-Sigmatropic rearrangement,[1,2]- Sigmatropic rearrangement,Rhodium catalysis

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