A plier-shaped binary molecular wheel B7Mg4+ cluster: hybrid in-plane heptacoordination, double π/σ aromaticity, and electronic transmutation
New Journal of Chemistry（2023）
Abstract
A plier-shaped charge-transfer [Mg2]2+[Mg2B7]− complex cluster exhibits double 6π/6σ aromaticity, whose hybrid molecular wheel structure is rationalized using the concept of electronic transmutation.
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Key words
wheel,transmutation,plier-shaped,in-plane
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