Structural, magnetic and phase transition properties in S = ½ radical solid solutions of [F_xCl_1−x-BzPy][Ni(mnt)₂] (x = 0.07–0.87)

Inorganic Chemistry Frontiers（2023）

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摘要

The S = ½ spin chain salts [FxCl1−x-BzPy][Ni(mnt)2] (0–1) show a phase transition, and an anomalous change of TC and J/kB with x.

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radical solid solutions,phase transition properties,solid solutions

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Structural, magnetic and phase transition properties in S = ½ radical solid solutions of [FxCl1−x-BzPy][Ni(mnt)2] (x = 0.07–0.87)