Global sea level changes or local tectonics? Pliocene, Miocene and Oligocene biomarkers in cored sedimentary rocks from IODP Expedition 317, Canterbury Basin, New Zealand

The various influences of global sea level (eustasy) and local tectonic changes on sedimentation processes in continental margin deposits are important topics in sedimentary research. International Ocean Discovery Program Expedition 317 to the Canterbury Basin, on the eastern margin of the South Island of New Zealand, provided an opportunity to study sediment geochemistry in contrasting depositional settings, from mid-shelf to upper continental slope sedimentary rocks from the Eocene to the Holocene. This paper provides the first examination of the organic geochemical record from Pliocene, Miocene, and Oligocene sediment samples recovered during the expedition from the U1351, U1352, and U1353 sites, using bulk geochemistry and hydrocarbon distributions, including biomarkers. The main aim of this research was to correlate changes in organic accumulation with local tectonic activity and global climate changes that occurred in the Miocene. There is good preservation of C11 to C35 n-alkanes, with varying predominance of odd-over-even chain length n-alkanes, and much variation in the terrigenous/aquatic ratio over the cores. Based on biomarker and Rock Eval parameters, thermal maturity varies from low in the Pliocene, to early oil window in the deeper Miocene and Oligocene sedimentary rocks. The pristane/phytane ratios for the three cores indicate anoxic to oxic depositional environments. Marine organic matter input is indicated by the high C30 sterane index, whilst high relative amounts of oleanane, C24 tetracyclic terpane, and C29 steranes indicates major terrigenous organic matter input. Local tectonic activity is suggested to have had a significant influence on the accumulation of the organic matter in the Canterbury Basin. The influence of eustasy and global sea temperature variations are suggested for the periods < 14 Ma, 12-7 Ma, and similar to 6 Ma. An increase in terrigenous organic matter input during the late Miocene correlates with the uplift of the Southern Alps and an increase in the continental slope angle for the South Island of New Zealand.