Durable superhydrophobic coatings based on CNTs-SiO2gel hybrids for anti-corrosion and thermal insulation

PROGRESS IN ORGANIC COATINGS(2023)

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摘要
When steel structure buildings appear more frequently in our lives, the anti-corrosion and thermal insulation capacity of steel as the substrate is an inevitable difficult problem. To solve this problem, we propose a carbon nanotube silica aerogel hybrid (CNTs-SiO2gel hybrids), which is a new type of nanoparticle obtained by grafting the modified silica aerogel onto carbon nanotubes. After that, the superhydrophobic coating was prepared on Q235 steel by simple one-step spraying. The prepared superhydrophobic coating has a stable micro nanolayered structure and excellent hydrophobicity, with a contact angle of 168.7 +/- 1 degrees and a sliding angle of 4.5 +/- 0.4 degrees. The superhydrophobic coating can withstand various mechanical and chemical durability tests and maintained good superhydrophobic properties. The electrochemical experimental analysis shows that the corrosion current den-sity of CNTs-SiO2gel hybrids superhydrophobic coating is 1.55 x 10-7 A/cm2 is three orders of magnitude lower than steel plate (1.07 x 10-4 A/cm2), indicating that CNTs-SiO2gel hybrids have excellent corrosion resistance. CNTs-SiO2gel hybrids superhydrophobic coating has achieved certain thermal insulation performance compared with ordinary CNTs-SiO2 coating. CNTs-SiO2gel hybrids superhydrophobic coating, which has both anti-corrosion and thermal insulation capabilities, will certainly expand the practical application of super-hydrophobic coating.
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关键词
Superhydrophobic coating, Anti-corrosion, Carbon nanotubes, Thermal insulation
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