Hydrochemical characteristics of groundwater in a plain river network region: Establishing linkages between source and water quality variables

The chemical characteristics of groundwater can indicate water quality condition and provide useful information for pollution source identification. This study aimed to understand the effects of dissolved organic matter (DOM) on ionic composition of groundwater and identify the main ions and sources of pollution. The Lake Taihu is a typical eutrophic lake in China. In this study, the hydrochemical composition of groundwater in the surrounding aquifer of Lake Taihu Basin was analyzed. The results showed that the values of water quality index (WQI) range from 13.29 to 56.26 (good water quality). The dominant hydrochemical type of groundwater was Ca-Mg-HCO3 type, and the rock dominance was the major mechanism controlling the groundwater chemistry. With an increasing concentration in dissolved organic carbon (DOC), the Na+, Mg2+, and HCO3- concentrations all showed a sharp increase followed by a slow increase, while the NO3- concentration showed an opposite trend, indicating the DOM can affect the ions composition. In addition, K+ was positively correlated with NO3-, As, and Cd. Hence, DOM input may directly or indirectly change the hydrochemistry of groundwater. Besides, the NO3- concentration in groundwater was much higher than that in Lake Taihu, indicating that the NO3- in groundwater mainly came from surface soil leaching. The anthropogenic sources are probably the main sources of different ions, including K+, NO3-, As, and Cd. This study can help to better understand the effects of lake eutrophication on groundwater and its pathways.