Supercooled Liquid Ga Stretchable Electronics

By controlling the properties of its medium, supercooled liquid Ga (SLGa) based stretchable remains stretchable at -22 degrees C, i.e., 52 degrees C below its thermo-dynamic melting point of Ga. Thus far, our oldest deposited SLGa circuit and film have remained liquids for 2 years at room temperature. The study investi-gates the crystallization of SLGa triggered by the surface energy of nucleation agents, temperature, circuit cross-section, and mechanical impact. Based on these parameters, a method is presented to integrate electronic components with SLGa circuits without compromising its supercooling effect. Further, the large stiffness variation induced by phase transition is demonstrated in dif-ferent applications. For the desired stiffness variation, the crystallization rate can be controlled by varying the temperature and cross-section area. Finally, spray-printing an ink of microscale SLGa microscale particles can confor-mally pattern Ga on a rough surface, e.g., to fabricate a stretchable array of SLGa microelectrodes. A smart patch with stretchable SLGa electrode arrays records human electrocardiogram signals in cold water and does not stain the skin after use. Its low and stable impedance in water will enable novel applications in wearable electronics.