Self-assembly of achiral building blocks into chiral cyclophanes using non-directional interactions

Laurent Vial,Julien Leclaire,Florent PERRET,Ivan Huc,Pradeep Kumar Mandal,Elise Dumont,Olivier Cala,Nicolas Vanthuyne,Ana M Belenguer, Christian Duchamp, Titouan Chetot,Emeric Jeamet,Pierre-Thomas Skowron,Benjamin Ourri,Yuan Zhang

Chemical Science（2023）

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摘要

The stereoselective assembly of achiral constituents through a single spontaneous process into complex covalent architectures bearing multiple stereogenic elements still remain a challenge for synthetic chemists. Here, we show that...

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关键词

achiral cyclophanes,achiral building blocks,self-assembly,non-directional

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