Open honeycomb frameworks of sulphides AHg₄Ga₅S₁₂ (A = Rb, Cs) exhibiting infrared nonlinear optical properties

Xiao-Yu Lou,Yu Zhou,Wen-Fa Chen,Xiao-Ming Jiang,Bin-Wen Liu,Guo-Cong Guo

Dalton Transactions（2023）

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摘要

Crystalline materials AHg4Ga5S12 (A = Rb, Cs) with diamond-like anionic frameworks constructed by the aligned arrangement of tetrahedral units exhibit moderate second-order nonlinear optical (NLO) responses and high laser-induced damage thresholds.

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Open honeycomb frameworks of sulphides AHg4Ga5S12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties

Open honeycomb frameworks of sulphides AHg₄Ga₅S₁₂ (A = Rb, Cs) exhibiting infrared nonlinear optical properties