Intracluster ligand rearrangement: an NMR-based thermodynamic study

Daniele Rosa-Gastaldo,Marion Pupier, Giorgi Meshvildishvili,Jasmine Viger-Gravel,Thomas Bürgi

Nanoscale（2023）

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摘要

Combining variable-temperature NMR experiments and dynamic-NMR simulations, we extract the thermodynamic activation parameters of a new exchange reaction on atomically precise metal nanoclusters: the intracluster ligand rearrangement reaction (LRR).

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