Batch and continuous flow asymmetric synthesis of anabolic-androgenic steroids via single-cell biocatalytic ∆1-dehydrogenation and C17β-carbonyl reduction cascade
Green Chemistry(2023)
摘要
Chemoenzymatic asymmetric synthesis of anabolic-androgenic steroid (+)-boldenone (3) and its prodrug (+)-boldenone undecylenate (4) was accomplished starting from commercially available 4-androstene-3,17-dione (4-AD, 1) under both batch and continuous flow conditions....
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