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Controllable carbonyl-assisted C(sp3)–C(sp3) bond reduction and reorganization

Shengke Wang,Yitu Wang, Kun Hu, Kai Wang,Xigeng Zhou

Organic Chemistry Frontiers（2023）

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Abstract
Unprecedentedly preferential reduction of unstrained C(sp3)–C(sp3) bond over ketone, hydrogenative [2+2+2]-cycloreversion of 2,4-diacylcyclohexanols, and cyclizative degradation of poly(vinylketone) have been achieved by organolanthanide catalysis.
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Key words
bond reduction,carbonyl-assisted
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